Preparation of silica glass by flame hydrolysis and its hydroxyl group increment regulation mechanism

DENG Xiufeng; CUI Dongming; KONG Ming; XIE Kang; LIU Zhijian; CHENG Qing; CUI Zhengyan; LIANG Jinyu

您当前的位置：

首页 >

文章列表页 >

Preparation of silica glass by flame hydrolysis and its hydroxyl group increment regulation mechanism

Optical Materials | 更新时间：2026-01-05

- Preparation of silica glass by flame hydrolysis and its hydroxyl group increment regulation mechanism
- OPTICAL TECHNIQUE Vol. 51, Issue 6, Pages: 675-679(2025)
- 作者机构：
  
  1.武汉烽火锐拓科技有限公司，湖北武汉 430000
  2.烽火通信科技股份有限公司，湖北武汉 430000
- 作者简介：
- 基金信息：
- DOI：
  CLC： TP394.1;TH691.9
- Received：03 January 2025，
  
  Revised：2025-06-10，
  
  Published：20 November 2025
- 稿件说明：
移动端阅览
邓秀峰,崔东明,孔明等.火焰水解制备石英玻璃及其羟基增量调控机制[J].光学技术,2025,51(06):675-679.

DENG Xiufeng,CUI Dongming,KONG Ming,et al.Preparation of silica glass by flame hydrolysis and its hydroxyl group increment regulation mechanism[J].OPTICAL TECHNIQUE,2025,51(06):675-679.
邓秀峰,崔东明,孔明等.火焰水解制备石英玻璃及其羟基增量调控机制[J].光学技术,2025,51(06):675-679. DOI：

DENG Xiufeng,CUI Dongming,KONG Ming,et al.Preparation of silica glass by flame hydrolysis and its hydroxyl group increment regulation mechanism[J].OPTICAL TECHNIQUE,2025,51(06):675-679. DOI：

摘要

高羟基含量的石英玻璃具备耐宇宙射线辐照特性，在现代航空航天领域应用前景广阔。然而，现有火焰水解沉积等方法所制备的石英玻璃，其羟基浓度通常小于50ppm，无法满足耐辐照石英玻璃对高羟基含量的需求。针对该问题，文章讨论了石英玻璃中羟基的赋存形式、形成机制，分析了影响羟基含量的主控因素，形成了火焰水解合成石英玻璃过程中羟基增量调控理论。在此基础上，通过实验论证了羟基增量调控理论的可行性；结果显示，通过采用多方法协同的羟基增量调控策略，将石英玻璃中的羟基含量从1.2ppm提高至201.2ppm。

Abstract

Silica glass with high hydroxyl content is resistant to cosmic ray irradiation

which is promising for modern aerospace applications. However

the hydroxyl concentration of silica glass prepared by the flame hydrolysis deposition method is usually less than 50ppm

which cannot meet the demand for high hydroxyl content in irradiation-resistant silica glass. To address this problem

the forms and formation mechanism of hydroxyl groups in silica glass were discussed

the main factors affecting the hydroxyl content were analyzed

and thereby an incremental regulation theory of hydroxyl during the flame hydrolysis synthesis of silica glass was formed. On this basis

the relevant experiments were conducted to demonstrate the feasibility of the incremental regulation theory of hydroxyl. It was indicated by the results that the hydroxyl concentration in silica glass was increased from 1.2 to 201.2ppm by applying the synergistic incremental regulation strategy of hydroxyl with multiple methods.

关键词

Keywords

references

吴兴轩 , 朱满康 , 贾渊洁 , 等 . 从发明专利看石英玻璃合成工艺的研究与发展 [J ] . 硅酸盐通报 , 2013 , 32 （ 04 ）: 646 — 650+656 .

Wu Xingxuan , Zhu Mankang , Jia Yuanjie , et al . Review on synthesizing processes of fused silica from patents in latest decades [J ] . Bulletin of the Chinese Ceramic Society , 2013 , 32 （ 04 ）: 646 — 650+656 .

聂兰舰 , 王玉芬 , 向在奎 , 等 . 高性能光学合成石英玻璃的制备和应用 [J ] . 光学精密工程 , 2016 , 24 （ 12 ）: 2916 — 2924 .

Nie Lanjian , Wang Yufen , Xiang Zaikui , et al . Preparation and application of high-performance synthetic optical fused silica glass [J ] . Optics and Precision Engineering , 2016 , 24 （ 12 ）: 2916 — 2924 .

Faile S P , Roy D M . Mechanism of color center destruction in hydrogen impregnated radiation resistant glasses [J ] . Mater Res Bull , 1970 , 5 （ 6 ）: 385 .

王振林 , 成来飞 . 玻璃的辐照效应及耐辐照改性研究进展 [J ] . 材料导报 , 2017 , 31 （ 05 ）: 94 — 99 .

Wang Zhenlin , Cheng Laifei . Irradiation effects and irradiation resistance modification of glasses [J ] . Materials Reports , 2017 , 31 （ 05 ）: 94 — 99 .

魏来 , 凌雪 , 吴俊豪 , 等 . 玻璃材料的宏微观辐照效应 [J ] . 中国科学:物理学力学天文学 , 2024 , 54 （ 08 ）: 5 — 30 .

Wei Lai , Lin Xue , Wu Junhao , et al . Macroscopic and microscopic radiation effects on glass materials [J ] . Scientia Sinica （Physica , Mechanica & Astronomica）, 2024 , 54 （ 08 ）: 5 — 30 .

张晓强 , 孙元成 , 贾永雷 , 等 . 不同类型石英玻璃的振动能量损耗特性对比分析 [J ] . 硅酸盐通报 , 2022 , 41 （ 11 ）: 4095 - 4102 .

Zhang Xiaoqiang , Sun Yuancheng , Jia Yonglei , et al . Comparative analysis of mechanical energy loss in different types of silica glass [J ] . Bulletin of the Chinese Ceramic Society , 2022 , 41 （ 11 ）: 4095 — 4102 .

Shelby J E . Hydrogen, hydride and water in amorphous SiO 2 Protonic species in vitreous silica [J ] . Journal of Non-Crystalline Solids , 1994 , 179 : 138 — 147 .

P W McMillan , A Chlebik . The effect of hydroxyl ion content on the mechanical and other properties of soda-lime-silica glass [J ] . Journal of Non-Crystalline Solids , 1980 , 38 : 509 — 514 .

孙元成 , 赵慧峰 , 孙丽娜 . 中国建材总院新材料护航“天宫二号” [J ] . 中国建材 , 2016 , 10 : 78 .

Sun Yuancheng , Zhao Huifeng , Sun Lina . China National Building Materials Academy's new materials escort “Tiangong-2 ” [J ] . China Building Materials , 2016 , 10 : 78 .

周永恒 . 石英玻璃及原料中羟基的研究 [D ] . 北京 : 中国建筑材料科学研究院 , 2002 : 11 — 13 .

Zhou Yongheng . Research on the hydroxyl groups in the silica glass and its materials [D ] . Beijing : China Building Materials Academy , 2002 : 11 — 13 .

符博 , 王慧 , 贾亚男 , 等 . 石英玻璃中羟基对其性能的影响 [J ] . 硅酸盐通报 , 2017 , 36 : 336 — 339 .

Fu Bo , Wang Hui , Jia Yanan , et al . Effect of hydroxylation in quartz glass on its properties [J ] . Bulletin of the Chinese Ceramic Society , 2017 , 36 : 336 — 339 .

周永恒 , 顾真安 . 石英玻璃及其水晶原料中羟基的研究 [J ] . 硅酸盐学报 , 2002 , 30 （ 3 ）: 357 — 361 .

Zhou Yongheng , Gu Zhenan . Study on hydroxyl in quartz glass and quartz raw materials [J ] . Journal of the Chinese Ceramic Society , 2002 , 30 （ 3 ）: 357 — 361 .

姚用真 . VAD法的脱水与透明化技术 [J ] . 光纤与电缆及其应用技术 , 1984 ,（ 01 ）: 51 — 58 .

Yao Yongzhen . Dehydration and clarification technology of VAD method [J ] . Optical Fiber & Electric Cable and Their Applications , 1984 ,（ 01 ）: 51 — 58 .

黄泽宇 , 黄耀松 , 陈靖 , 等 . 入口条件对D4合成石英玻璃的影响 [J ] . 燃烧科学与技术 , 2018 , 24 （ 06 ）: 477 — 486 .

Huang Zeyu , Huang Yaosong , Chen Jing , et al . Effects of entrance conditions on fused silica glass synthesis using D4 [J ] . Journal of Combustion Science and Technology , 2018 , 24 （ 06 ）: 477 — 486 .

Peter B McGinnis , James E Shelby . Diffusion of water in float glass melts [J ] . Journal of Non-Crystalline Solids , 1994 , 177 : 381 — 388 .

Peter B McGinnis , James E Shelby . Diffusion of water in vitreous silica [J ] . Journal of Non-Crystalline Solids , 1994 , 179 : 185 — 193 .

Velmuzhov A P , Sukhanov M V , Churbanov M F , et al . Behavior of hydroxyl groups in quartz glass during heat treatment in the range 750-950°C [J ] . Inorganic Materials , 2018 , 54 （ 09 ）: 925 — 930 .

聂兰舰 , 向在奎 , 饶传东 , 等 . 石英玻璃的制备方法及石英玻璃 : 201610798851.4 [P ] . 2016-08-31 .

Nie Lanjian , Xiang Zaikui , Rao Chuangdong , et al . Silica glass and its preparation method : 201610798851.4 [P ] . 2016-08-31 .

马千里 . 高纯石英玻璃制备过程的研究和工艺优化 [D ] . 武汉 : 华中科技大学 , 2020 : 72 — 83 .

Ma Qianli . Study and process optimization towards the fabrication of high-purity silica glass [D ] . Wuhan : Huazhong University of Science and Technology , 2020 : 72 — 83 .

Yunhao Xi , Nengwu Zhu , Junlin Huang , et al . Na 2 O induced stable heavy metal silicates phase transformation and glass network depolymerization [J ] . Journal of Cleaner Production , 2022 , 380 : 135009 .

Kai Bai , Kemian Qin , Zhaoxuan Jin , et al . Water corrosion mechanisms in ternary sodium borosilicate glass under varied pH conditions [J ] . Ceramics International , 2025 , 51 （ 12 ）: 15149 — 15159 .

中国国家标准化管理委员会 . GB/T 12442-2019 中华人民共和国国家标准: 石英玻璃中羟基含量检验方法 [S ] . 北京 : 中国标准出版社 , 2019 .

National Standardization Administration of the People's Republic of China . GB/T 12442-2019 The People's Republic of China Public Security National Standards: Test method for the hydroxyl groups content of silica glass [S ] . Beijing : China Standard Press , 2019 .

梁海霞 . 玻璃管中羟基含量的测定 [J ] . 江西化工 , 2013 （ 04 ）: 159 — 161 .

Liang Haixia . Measurement for the hydroxyl content of glass tube [J ] . Jiangxi Chemical Industry , 2013 （ 04 ）: 159 — 161 .

刘伟 , 王莉丽 , 刘连利 , 等 . 石英玻璃中羟基含量测定的红外光谱法研究 [J ] . 渤海大学学报（自然科学版） , 2008 , 29 （ 04 ）: 332 — 335 .

Liu Wei , Wang Lili , Liu Lianli , et al . Determination of hydroxy in quartz glass by infrared spectrology [J ] . Journal of Bohai University （Natural Science Edition） , 2008 , 29 （ 04 ）: 332 — 335 .

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Development of Two-dimensional uniform light film of holographic Polymer-dispersed liquid crystal based on Five-wave interference

Fluorescence properties of divalent cobalt doped yttrium aluminate garnet transparent ceramics under the ultraviolet excitation

Related Author

CAI Jia

LU Siyu

XU Hai

LI Yichen

ZHENG Jihong

RAO Cong

LIN Hui

Related Institution

Shanghai Key Lab of Modern Optical System, School of Optical -electrical and Computer Engineering, University of Shanghai Science and Technology

Engineering Research center of Optical Instruments and systems, Ministry of Education, School of Optical-Electrical and Computer Engineering, University of Shanghai for Science and Technology

⁰