火焰水解制备石英玻璃及其羟基增量调控机制

邓秀峰; 崔东明; 孔明; 谢康; 刘志坚; 程青; 崔争艳; 梁进宇

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火焰水解制备石英玻璃及其羟基增量调控机制

光学材料 | 更新时间：2026-01-05

- 火焰水解制备石英玻璃及其羟基增量调控机制
- Preparation of silica glass by flame hydrolysis and its hydroxyl group increment regulation mechanism
- 光学技术 2025年51卷第6期页码：675-679
- 作者机构：
  
  1.武汉烽火锐拓科技有限公司，湖北武汉 430000
  2.烽火通信科技股份有限公司，湖北武汉 430000
- 作者简介：
  
  邓秀峰（1994— ），男，工程师，博士，从事无机非金属材料研究。xfdeng1228@fiberhome.com
  dmcui@fiberhome.com
- 基金信息：
  
  湖北省重点研发计划项目(2023BAB009);武汉市科技计划项目(2023030103010001)
- DOI：
  中图分类号： TP394.1;TH691.9
- 收稿：2025-01-03，
  
  修回：2025-06-10，
  
  纸质出版：2025-11-20
- 稿件说明：
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邓秀峰,崔东明,孔明等.火焰水解制备石英玻璃及其羟基增量调控机制[J].光学技术,2025,51(06):675-679.

DENG Xiufeng,CUI Dongming,KONG Ming,et al.Preparation of silica glass by flame hydrolysis and its hydroxyl group increment regulation mechanism[J].OPTICAL TECHNIQUE,2025,51(06):675-679.
邓秀峰,崔东明,孔明等.火焰水解制备石英玻璃及其羟基增量调控机制[J].光学技术,2025,51(06):675-679. DOI：

DENG Xiufeng,CUI Dongming,KONG Ming,et al.Preparation of silica glass by flame hydrolysis and its hydroxyl group increment regulation mechanism[J].OPTICAL TECHNIQUE,2025,51(06):675-679. DOI：

摘要

高羟基含量的石英玻璃具备耐宇宙射线辐照特性，在现代航空航天领域应用前景广阔。然而，现有火焰水解沉积等方法所制备的石英玻璃，其羟基浓度通常小于50ppm，无法满足耐辐照石英玻璃对高羟基含量的需求。针对该问题，文章讨论了石英玻璃中羟基的赋存形式、形成机制，分析了影响羟基含量的主控因素，形成了火焰水解合成石英玻璃过程中羟基增量调控理论。在此基础上，通过实验论证了羟基增量调控理论的可行性；结果显示，通过采用多方法协同的羟基增量调控策略，将石英玻璃中的羟基含量从1.2ppm提高至201.2ppm。

Abstract

Silica glass with high hydroxyl content is resistant to cosmic ray irradiation

which is promising for modern aerospace applications. However

the hydroxyl concentration of silica glass prepared by the flame hydrolysis deposition method is usually less than 50ppm

which cannot meet the demand for high hydroxyl content in irradiation-resistant silica glass. To address this problem

the forms and formation mechanism of hydroxyl groups in silica glass were discussed

the main factors affecting the hydroxyl content were analyzed

and thereby an incremental regulation theory of hydroxyl during the flame hydrolysis synthesis of silica glass was formed. On this basis

the relevant experiments were conducted to demonstrate the feasibility of the incremental regulation theory of hydroxyl. It was indicated by the results that the hydroxyl concentration in silica glass was increased from 1.2 to 201.2ppm by applying the synergistic incremental regulation strategy of hydroxyl with multiple methods.

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references

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